Roberto Soldado scored twice as Valencia beat Rayo Vallecano 4-0 to keep their Champions League hopes alive.
Atletico Madrid were held to a 1-1 draw at home by Valencia and missed the chance to return to second in La Liga.
Valencia beat 10-man Real Betis 3-0 at the Mestalla to move fifth in La Liga.
Substitute Iker Muniain secured all three points for Athletic Bilbao as they shocked Valencia 1-0 in La Liga at the San Mames.
Leonardo's assertion that Paris St Germain are made for the Champions League but not for low-key Ligue 1 matches could backfire on Wednesday if they do not show
Valencia have agreed to exercise their option to buy on-loan Paraguay striker Nelson Valdez from Russian side Rubin Kazan.
Paris St Germain's trip to Valencia in the Champions League on Tuesday pits the wealthy French team against one of many La Liga clubs struggling to stay
Cristiano Ronaldo warmed up for Real Madrid's Champions League tie with Manchester United by hitting a hat-trick against Sevilla.
Valencia's Nelson Valdez came off the bench to snatch a last-gasp 1-0 win at Celta Vigo and give his side a lift.
Valencia's Nelson Valdez came off the bench to snatch a last-gasp 1-0 win at Celta Vigo in La Liga on Saturday and give his side a morale boost before they play
Ricardo Costa nodded the winner in stoppage time as Valencia came from behind to complete a 3-2 win over nine-man Deportivo.
Adrian fired second-placed Atletico Madrid to a 1-0 win over Celta Vigo to maintain their perfect home record.
Valencia captain Roberto Soldado struck in the opening minute to set them on their way to a 4-2 home win over Getafe.
Valencia condemned Lille to their worst ever Champions League campaign with a 1-0 victory in France in Group F.
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