Siena ended Lazio's unbeaten away run in Serie A with a crushing 4-0 home win over Edy Reja's sluggish 10-man team.
Lazio have confirmed that the club have completed four new signings including Federico Marchetti and Marius Stankevicius.
Osasuna picked up a vital victory in their bid to beat the drop from La Liga with a hard-earned 1-0 triumph against Valencia.
Round-up: Real Madrid enjoyed a carefree 6-3 victory at Valencia to close the gap on Liga leaders Barcelona to five points.
Round-up: Valencia improved their chances of securing third place in La Liga when they won 3-0 at bottom club Almeria.
Liga joint-top scorers Cristiano Ronaldo and Lionel Messi, with 27 goals each, were both working to shake off injuries in time for Saturday.
Valencia suffered the archetypal European hangover as they crashed to a 4-0 hammering at lowly Real Zaragoza.
An equaliser from Giuseppe Rossi earned Villarreal a 1-1 home draw with Valencia to keep them third in La Liga.
Injury-hit Spain may have to rely on some unfamiliar names including uncapped Aritz Aduriz in their Euro 2012 qualifier against Lithuania.
A round-up of all the transfer deadline deals with Eidur Gudjohnsen joining Stoke and Rafael van der Vaart securing his move to Tottenham.
Factbox on Serie A clubs after the transfer window closed (all amounts in euros, last season's positions in brackets):
Details on all the transfers made by Liga clubs during the transfer window.
Valencia have agreed to sign Lithuania defender Marius Stankevicius on loan from Sampdoria this season.
Valencia agree to sign Lithuania defender Marius Stankevicius on loan from Sampdoria.
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