Eight players will have a final chance to claim a place in Mexico's World Cup squad in the friendly against Nigeria.
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Giovani dos Santos and Ikechukwu Uche each struck twice for Villarreal in a 5-1 drubbing of Real Sociedad in La Liga.
Neymar broke into double figures for the season as his brace helped Barcelona to a narrow 2-1 win over Villarreal.
Barcelona will be looking to Neymar to add to his hat-trick against Celtic as the Catalan side look to get back to winning ways.
Mexico have confirmed Miguel "Piojo" Herrera will coach the national squad at the World Cup finals in Brazil next year.
Villarreal's Mexican forward Giovani Dos Santos sustained a muscle tear in their La Liga win at Elche on Monday.
Mexico coach Miguel Herrera has left their big-name European exiles, including Manchester United's Javier Hernandez, out of the squad for this month's 2014
Round-up: David Villa struck twice as Atletico Madrid stayed hard on the heels of Barcelona with a 5-0 win against Real Betis.
Barcelona's Mexico midfielder Jonathan Dos Santos needs knee surgery and will be out for around six months.
Mexico's new coach Miguel Herrera included 10 players from his club America for his World Cup playoff squad.
Round-up: Villarreal went third in La Liga with a 3-0 win over Granada while Malaga suffered a shock 1-0 defeat by Osasuna.
Guillermo Ochoa, who plays in goal for French Ligue 1 team Ajaccio, has been called up to Mexico's squad.
Gareth Bale did not enjoy a winning start to his Real Madrid career but the world's most expensive player earned praise from new coach Carlo Ancelotti.
Gareth Bale scored on his Real Madrid debut, but Villarreal put forth an impressive performance to secure a 2-2 draw.
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